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Exploring the crystal structure and properties of ytterbium orthoantimonate under high pressure

dc.contributor.authorGarg, Alka B
dc.contributor.authorLópez Moreno, Sinhué
dc.contributor.authorBotella Vives, Pablo
dc.contributor.authorGomis, Oscar
dc.contributor.authorBandiello, Enrico
dc.contributor.authorOsman, Hussien
dc.contributor.authorPopescu, Catalin
dc.contributor.authorErrandonea, Daniel
dc.date.accessioned2024-05-30T21:28:16Z
dc.date.available2024-05-30T21:28:16Z
dc.date.issued2023
dc.identifier.citationGarg, Alka & López, Sinhué & Botella Vives, Pablo & Gomis, Oscar & Bandiello, Enrico & Osman, Hussien & Popescu, Catalin & Errandonea, Daniel. (2023). Exploring the crystal structure and properties of ytterbium orthoantimonate under high pressure. Dalton Transactions. 52. 10.1039/D3DT02480F.
dc.identifier.urihttp://hdl.handle.net/11627/6535
dc.description.abstractThe crystal structure of YbSbO4 was determined from powder X-ray diffraction data using the Rietveld method. YbSbO4 is found to be monoclinic and isostructural to ?-PrSbO4. We have also tested the influence of pressure on the crystal structure up to 22 GPa by synchrotron powder X-ray diffraction. No phase transition was found. The P–V equation of state and axial compressibilities were determined. Experiments were combined with density-functional theory calculations, which provided information on the elastic constants and the influence of pressure in the crystal structure and Raman/infrared phonons. Results are compared with those from other orthoantimonates. Reasons for the difference in the high-pressure behaviour of YbSbO4 compared with most antimony oxides will be discussed.
dc.publisherRoyal Society of Chemistry
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectBehavior
dc.subject.classificationQUÍMICA
dc.titleExploring the crystal structure and properties of ytterbium orthoantimonate under high pressure
dc.typearticle
dc.identifier.doihttps://doi.org/10.1039/d3dt02480f
dc.rights.accessAcceso Abierto


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